An Electron Impact Study of Ionization and Dissociation of Trimethylsilanes
An Electron Impact Study of Ionization and Dissociation of Trimethylsilanes
复制标题
三甲基硅烷电离和离解的电子轰击研究
DOI：
10.1021/ja00951a012
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发表时间：
1965
影响因子：
15
通讯作者：
L. H. Sommer
中科院分区：
文献类型：
--
作者：
G. G. Hess;F. W. Lampe;L. H. Sommer
在过去的20年里，电子碰撞研究为化学家提供了大量关于气体分子、离子和自由基的能量性质的知识。1· 2这些热化学信息中有很大一部分与碳化合物有关，并且在许多涉及碳氢化合物和含有第一个长周期元素的衍生物的反应的研究中证明是很有价值的。然而，在类似的有机硅化合物中，这种能量信息却很少，尽管近年来人们对有机硅化学的兴趣不断增加。此外，即使在公开文献中可获得的微薄数据中，也存在许多重大差异。6· 6
During the last 2 decades electron impact studies have provided chemists with a considerable body of knowledge concerning energetic properties of gaseous molecules, ions, and free radicals. 1· 2 A very large fraction of this thermochemical information pertains to compounds of carbon and has proved to be of great value in many studies of reactions involving hydrocarbons and derivatives containing elements of the first long period.However, in the analogous organosilicon compounds very little such energetic information is available3· 4 even though in recent years interest in organosilicon chemistry has been continually increasing. More-over, even among the meager data available in the open literature there are numerous significant discrepancies. 6· 6