Fe-Ga multiple bonding? Synthesis, spectroscopic and structural characterization of a transition metal complex containing a cationic two-coordinate gallium centre.
Fe-Ga multiple bonding? Synthesis, spectroscopic and structural characterization of a transition metal complex containing a cationic two-coordinate gallium centre.
复制标题
Fe-Ga多重键合？
DOI：
10.1039/b405943c
复制
发表时间：
2004
影响因子：
4.9
通讯作者：
Li
中科院分区：
文献类型：
--
作者：
Natalie R. Bunn;S. Aldridge;Deborah L. Coombs;A. Rossin;D. Willock;Cameron Jones;Li
本文报道了含对称桥联双配位镓原子和离域Fe-Ga-Fe π体系的阳离子铁配合物[（（η 5-C5 Me 5）Fe（CO）2））2Ga]+[BAr（f）4]- [Ar（f）= C6 H3（CF 3）2- 3，5]的合成和表征。
This communication reports the synthesis and characterization of the cationic iron complex [((eta5-C5Me5)Fe(CO)2))2Ga]+[BAr(f)4]- [Ar(f) = C6H3(CF3)2-3,5] containing a symmetrically bridging two-coordinate gallium atom and a delocalised Fe-Ga-Fe pi system incorporating partial Fe-Ga multiple bond character.