POLY(p-PHENYLENE SULFIDE)—AN OVERVIEW OF AN IMPORTANT ENGINEERING THERMOPLASTIC
POLY(p-PHENYLENE SULFIDE)—AN OVERVIEW OF AN IMPORTANT ENGINEERING THERMOPLASTIC
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聚对苯硫醚——重要工程热塑性塑料概述
DOI：
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发表时间：
1989
期刊：
影响因子：
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通讯作者：
G. Wilkes
中科院分区：
文献类型：
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作者：
L. Lopez;G. Wilkes
摘要在众多的高温聚合物中，基于芳香族单元的聚合物，如聚(2，6-二甲基苯氧基)(PPO)、聚苯硫醚(PPS)、聚醚醚酮(PEEK)和聚醚砜(PES)，由于其良好的耐热性和耐化学性，近年来引起了人们的广泛关注。PPS是其中一种聚合物，也是一种重要的高强度/高温工程热塑性塑料，在热塑性复合材料的成型树脂、纤维和基质等技术应用中得到了越来越多的应用。聚苯硫醚由对苯基单元和硫键交替组成。已知的第一个合成它的报告是由Grivesse于1898年[1]提出的。然而，对PPS合成的兴趣直到1948年才开始，当时Macallum 121描述了通过对二氯苯与碳酸钠和硫的熔融反应制备苯硫醚聚合物。对Lenz及其同事合成PPS的进一步研究[3-5]，以及后来的Edmo…
Abstract Among the various high temperature polymers, those based on aromatic units, such as poly(2, 6-dimethylphenylene oxide) (PPO), poly(pheny1ene sulfide) (PPS), poly(ether ether ketone) (PEEK), and poly(ether sulfone) (PES), have attracted much attention in the last few years due to their good thermal and chemical resistance. One of these polymers, PPS, is also an important high strength/high temperature engineering thermoplastic that is finding increasing use in technological applications such as molding resins, fibers, and matrices for thermoplastic composites. PPS consists of para-phenylene units alternating with sulfide linkages. The first known report of its synthesis was by Grenvesse in 1898 [1]. However, interest in the synthesis of PPS only began in 1948 when Macallum 121 described the preparation of phenylene sulfide polymers by the melt reaction of p-dichlorobenzene with sodium carbonate and sulfur. Further investigation on the synthesis of PPS by Lenz and coworkers [3–5], and later by Edmo...