Chlor-alkali technology: fundamentals, processes and materials for diaphragms and membranes

Chlor-alkali technology: fundamentals, processes and materials for diaphragms and membranes
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DOI:
10.1533/9780857097347.2.384
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发表时间:
2013-01-01
期刊:
HANDBOOK OF MEMBRANE REACTORS, VOL 2: REACTOR TYPES AND INDUSTRIAL APPLICATIONS
影响因子:
--
通讯作者:
Millet, P.
Millet, P.
中科院分区:
其他
文献类型:
--
作者:
Millet, P.

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离子导电材料用作电解槽中的槽隔板,用于在电极之间携带电荷和分离在每个电极处形成的产物的双重目的。本章的目的是概述氯碱技术和相关的电池隔板。在对氯碱工艺进行简要的历史回顾后,第9.1节详细介绍了主要的反应特性(热力学、电池反应和动力学)。第9.2节介绍了主要的氯碱技术。第9.3节(隔膜材料)和第9.4节(膜材料)中描述了主要电池隔板。9.5节介绍了一些改进的电解概念。
Ion-conducting materials are used as cell separators in electrolysis cells for the double purpose of carrying electric charges between electrodes and separating the products formed at each electrode. The purpose of this chapter is to provide an overview of chlor-alkali technology and associated cell separators. After a brief historical review of the chlor-alkali process, the main reaction characteristics (thermodynamics, cell reactions and kinetics) are detailed in Section 9.1. Main chlor-alkali technologies are described in Section 9.2. Main cell separators are described in Section 9.3 (diaphragm materials) and in Section 9.4 (membrane materials). Some improved electrolysis concepts are described in Section 9.5.