Superelectrophilic activation of 1-nitronaphthalene in the presence of aluminum chloride. Reactions with benzene and cyclohexane.
Superelectrophilic activation of 1-nitronaphthalene in the presence of aluminum chloride. Reactions with benzene and cyclohexane.
复制标题
氯化铝存在下 1-硝基萘的超亲电活化。
DOI：
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发表时间：
2018
影响因子：
3.2
通讯作者：
K. Y. Koltunov
中科院分区：
文献类型：
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作者：
Zhongwei Zhu;A. Genaev;G. E. Salnikov;K. Y. Koltunov
1-硝基萘与苯顺利反应，在氯化铝存在下与环己烷选择性还原，分别生成2,4,4-三苯基-3,4-二氢萘-1(2H)-酮肟和5,6,7,8-四氢-1-萘胺。在 DFT 的基础上讨论了这些反应和相关反应的机理，从而深入了解 1-硝基萘与 AlCl3 配位的质子化行为。
1-Nitronaphthalene smoothly reacts with benzene and undergoes selective reduction with cyclohexane in the presence of aluminum chloride to give 2,4,4-triphenyl-3,4-dihydronaphthalen-1(2H)-one oxime and 5,6,7,8-tetrahydro-1-naphthylamine, respectively. The mechanistic aspects of these and related reactions are discussed on the basis of DFT, providing insight into the protonation behavior of 1-nitronaphthalene coordinated to AlCl3.