Novel Ultrahigh-Energy Materials
Novel Ultrahigh-Energy Materials
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DOI：
10.1007/s10573-005-0031-1
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发表时间：
2005-05
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影响因子：
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通讯作者：
M. B. Talawar;R. Sivabalan;S. N. Asthana;H. Singh
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文献类型：
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作者：
M. B. Talawar;R. Sivabalan;S. N. Asthana;H. Singh
本文综述了近年来在现代高能材料领域的研究进展，重点介绍了均配型多氮化合物。大量的量子化学研究已经预测了多氮化合物存在的可能性，不仅作为短暂的瞬态物种，而且以可分离的离散分子的形式存在。尽管有理论上的推测，除了100年前发现的根深蒂固的N1− 3之外，今天只知道少数的多氮离子。这些绿色分子与当今和未来最强大的HEMs（即六硝基六氮杂异伍兹烷（CL-20）和八硝基立方烷（ONC））相比提供大量能量的非凡潜力激发了推进剂和炸药工程师和技术人员的想象力。许多量子化学学校正在进行研究活动，以探索其他有前途的多氮化合物的可能性。在最近发现关键合成子/结构单元Mg（N5）2、N1+ 5SbF 1 - 6、N1+ 5SbF 11、N1+5、N1+ 5SnF 6和N1+5Sn（CF 3）4之后，丰富的多氮化合物正等待着被HEMS社区收获。在地球仪上都有雄心勃勃的计划来实现N60，这只能证明是一个生态友好的密集能源发电站。
This paper reviews the recent work carried out in the field of modern high-energy materials (HEMs) with the emphasis on homoleptic polynitrogen compounds. A large volume of quantum-chemical investigations have predicted the possibility of existence of polynitrogen compounds not only as short-lived transient species but also in the form of isolable discrete molecules. Despite the theoretical speculations, only a few polynitrogen ions are known today in addition to well-entrenched N1−3discovered almost 100 year ago. Extraordinary potential of these green molecules to deliver high amounts of energy in comparison with today’s and tomorrow’s most powerful HEMs, namely, hexanitrohexaazaisowurtzitane (CL-20) and octanitrocubane (ONC), has fuelled the imagination of propellant and explosive engineers and technologists. Research activities are in progress in many quantum-chemical schools to explore the possibility of other promising polynitrogen compounds. After the recent discovery of key synthons/building blocks Mg(N5)2, N1+5SbF1−6, N1+5SbF11, N1+5, N1+5SnF6, and N1+5Sn(CF3)4, the wealth of polynitrogen compounds is just waiting to be harvested by the HEMs community. There are ambitious plans all over the globe to realize N60, which only prove a eco-friendly dense powerhouse of energy.