Abnormal Tin-Boron Exchange in the Attempted Synthesis of a Borylated Borole.
Abnormal Tin-Boron Exchange in the Attempted Synthesis of a Borylated Borole.
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尝试合成硼化硼中的异常锡硼交换
DOI：
10.1002/chem.201703810
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发表时间：
2017
期刊：
影响因子：
--
通讯作者：
K. Radacki
中科院分区：
文献类型：
--
作者：
H. Braunschweig;M. Dömling;S. Kachel;H. Kelch;T. Kramer;I. Krummenacher;C. Lenczyk;S. Lin;Z. Lin;C. Possiel;K. Radacki
Boroles are important motifs within functional materials. With the aim to prepare a pinacolboryl‐substituted derivative, the metallacycle transfer from corresponding zirconium and tin precursors has been explored. We show that the reaction of 1,1‐dimethyl‐2,3,4,5‐tetrapinacolborylstannole with dichloro(phenyl)borane does not provide the desired borole, but instead a stannyl‐substituted 1‐chloroboracyclopent‐3‐ene. Spectroscopic and structural details of this highly functionalized boracycle indicate that intramolecular interactions between the tin and oxygen atoms of the boryl substituents may account for the unexpected outcome of the tin‐boron exchange reaction.
