Stepwise Synthesis of a Mixed Valent Fe(II)-Fe(III) Complex in Cast Multibilayer Films1

Stepwise Synthesis of a Mixed Valent Fe(II)-Fe(III) Complex in Cast Multibilayer Films1
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流延多层膜中混合价 Fe(II)-Fe(III) 络合物的逐步合成1

DOI:
10.1080/10587259608046021
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发表时间:
1996
影响因子:
0.7
通讯作者:
T. Kunitake
T. Kunitake
中科院分区:
化学4区
文献类型:
--
作者:
N. Kimizuka;Toyokazu Handa;T. Kunitake

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本文采用分步合成法在多层膜层间合成了μ -氰化物Fe(Ⅱ)-Fe(Ⅲ)混价配合物。的Fe(II)-Fe(III)复合物显示出改变的吸收特性,在interbilayer从散装普鲁士蓝,可能是由于其几何限制的结构。
Abstract A mixed valent complex of μ -cyanide Fe(II)-Fe(III) was prepared by stepwise synthesis at the interlayer of multibilayer cast films. The Fe(II)-Fe(III) complex showed altered absorption characteristics in the interbilayer from those of bulk Prussian Blue, probably due to its geometrically confined structure.