The evidence for a preferential growth of a MnAs thin film on an as-preadsorbed Si(001) surface

The evidence for a preferential growth of a MnAs thin film on an as-preadsorbed Si(001) surface
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MnAs 薄膜在预吸附的 Si(001) 表面优先生长的证据

DOI:
10.1016/s0169-4332(98)00038-5
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发表时间:
1998
期刊:
影响因子:
--
通讯作者:
M. Oshima
M. Oshima
中科院分区:
--
文献类型:
--
作者:
M. Nakamura;Masaki Shuzo;K. Ono;H. Fujioka;Masaaki Tanaka;T. Nishinaga;Y. Watanabe;M. Oshima

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我们已经研究了使用光电子能谱的MnAs薄膜生长的初始阶段。使用具有Mn第一层和As第一层的两种类型的p型Si(001)衬底。结果表明,当先在Si上沉积1 ML的Mn时,在界面周围形成了锰硅化物(MnSi)和氧化硅。另一方面,当首先沉积As时,在界面处没有形成氧化硅。由于这种As钝化,首先沉积As的样品比先沉积Mn的样品具有更尖锐的界面和更好的膜质量。通过透射电子显微镜(TEM)观察了MnAs/Si体系中的界面合金。为了防止界面合金的形成,我们尝试在MnAs和Si之间插入GaAs,导致MnAs薄膜的生长,提高了薄膜质量。
We have investigated the initial stage of the MnAs film growth using photoelectron spectroscopy. Two types of p-type Si(001) substrates, with a Mn first layer and an As first layer were used. It is found that, a manganese silicide (MnSi) and silicon oxide are formed around the interface when 1 ML of Mn is deposited first on Si. On the other hand, there is no silicon oxide formed at the interface when As is deposited first. Because of this As-passivation, the sample on which As is deposited first, has the sharper interface and the better film quality than the Mn-first sample. The interfacial alloys were analyzed by cross-sectional transmission electron microscope (TEM) observation in the MnAs/Si system. To prevent the formation of interfacial alloys, we have tried to insert GaAs between MnAs and Si, resulting in the growth of MnAs film with improved film quality.