Fusarimine, a novel polyketide isoquinoline alkaloid, from the endophytic fungus Fusarium sp LN12, isolated from Melia azedarach
Fusarimine, a novel polyketide isoquinoline alkaloid, from the endophytic fungus Fusarium sp LN12, isolated from Melia azedarach
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Fusarimine，一种新型聚酮异喹啉生物碱，来自内生真菌 Fusarium sp LN12，从苦楝中分离出来
DOI：
10.1016/j.tetlet.2012.09.031
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发表时间：
2012-11-21
影响因子：
1.8
通讯作者：
Gao, Jin-Ming
中科院分区：
文献类型：
--
作者：
Yang, Sheng-Xiang;Xiao, Jian;Gao, Jin-Ming
Fusarimine (1) 是一种新型聚酮化合物衍生的异喹啉生物碱，具有罕见的 N-乙基-4-甲基-7-羧基异喹啉碳骨架，是从镰刀菌培养物中分离出来的。 LN-12，一种从苦楝叶中分离出来的内生真菌。 1的结构是在大量光谱数据的基础上阐明的，特别是通过2D NW：X射线晶体学分析证实了该结构并提供了绝对构型。 (C) 2012 Elsevier Ltd. 保留所有权利。
Fusarimine (1), a novel polyketide-derived isoquinoline alkaloid with a rare N-ethyl-4-methyl-7-carboxyisoquinoline carbon skeleton, was isolated from cultures of Fusarium sp. LN-12, an endophytic fungus isolated from the leaves of Melia azedarach. The structure of 1 was elucidated on the basis of extensive spectroscopic data, especially by 2D NW: X-ray crystallographic analysis confirmed the structure and delivered also the absolute configuration. (C) 2012 Elsevier Ltd. All rights reserved.