Inside Cover: [16]Cloverphene: a Clover‐Shaped cata‐Condensed Nanographene with Sixteen Fused Benzene Rings (Angew. Chem. Int. Ed. 1/2012)
Inside Cover: [16]Cloverphene: a Clover‐Shaped cata‐Condensed Nanographene with Sixteen Fused Benzene Rings (Angew. Chem. Int. Ed. 1/2012)
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DOI：
10.1002/anie.201107584
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发表时间：
2012-01
影响因子：
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通讯作者：
J. M. Alonso;Alba E. Díaz‐Álvarez;A. Criado;D. Pérez;D. Peña;E. Guitián
中科院分区：
文献类型：
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作者：
J. M. Alonso;Alba E. Díaz‐Álvarez;A. Criado;D. Pérez;D. Peña;E. Guitián
Cloverphenes是石墨烯型聚芳烃，其结构类似于三叶草叶子的三重对称。在他们的来文第173页及其后，D. Peña及其同事提出了一种纳米级[16] cloverphene衍生物的合成和性质，它由16个稠合苯环（总共22个苯环）和102个sp 2-杂化原子组成。该合成涉及顺序的[4+ 2]和[2+ 2+ 2]芳炔环加成反应。
Cloverphenes are graphene-type polyarenes, the structures of which resemble the threefold symmetry of clover leafs. In their Communication on page 173 ff., D. Peña and co-workers present the synthesis and properties of a nanosized [16] cloverphene derivative, which consists of 16 fused benzene rings (22 benzene rings in total) and 102 sp 2-hybridized atoms. The synthesis involves sequential [4+ 2] and [2+ 2+ 2] aryne cycloadditions.