Facile Fabrication of Multifunctional Metal Organic Framework Hollow Tubes To Trap Pollutants
Facile Fabrication of Multifunctional Metal Organic Framework Hollow Tubes To Trap Pollutants
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轻松制造多功能金属有机框架空心管以捕获污染物
DOI：
10.1021/jacs.7b10265
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发表时间：
2017-11-22
影响因子：
15
通讯作者：
Wang, Bo
中科院分区：
文献类型：
--
作者：
Chen, Yifa;Chen, Fan;Wang, Bo
污染物处理在现代社会中至关重要，并且通常需要繁琐的后处理和昂贵的设施。金属有机骨架（MOFs）由于其结构多样性和可调性，在污染物控制方面显示出良好的应用前景。我们在此报告了一个强大的模板冷冻干燥协议的制造多功能的MOF中空管状结构的空气和液体污染物过滤。各种中空管系统（例如，.“Janus”、“同轴”和“蜂窝”）。特别地，制备了用于高效捕获混合无机有机液体污染物的多层同轴MOF中空管，其过滤效率大于94%。此外，具有低压降（12 Pa，10 cm s（-1））的“蜂窝状”中空管以高效率（>92%）应用于颗粒物质过滤。由于MOFs具有丰富的结构和功能多样性，该协议有望将MOFs引入工业应用，以修复环境问题。
Pollutant treatment is critical in modern society and often requires tedious workup and expensive facilities. By virtue of structural diversity and tunability, metal organic frameworks (MOFs) have shown promise in pollutant control. We herein report a powerful templated freeze-drying protocol for the fabrication of multifunctional MOF hollow tubular structures for both air and liquid contaminants filtration. Various hollow tube systems (e.g.,. "Janus", "coaxial" and "cellular") are produced. Specially, a multilayer coaxial MOF hollow tube is prepared for highly efficient capture of mixed inorganic organic liquid contaminants with >94% filtration efficiency. Further, a "cellular" hollow tube with low pressure-drop (12 Pa, 10 cm s(-1)) is applied in particulate matter filtration with high efficiency (>92%). Given the rich structural and functional diversities, this protocol might bring MOFs into industrial applications to remediate environmental problems.