How reaction kinetics with time-dependent rate coefficients differs from generalized mass action
How reaction kinetics with time-dependent rate coefficients differs from generalized mass action
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DOI：
10.1002/cphc.200600081
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发表时间：
2006-07-17
期刊：
影响因子：
2.9
通讯作者：
Schnell, Santiago
中科院分区：
文献类型：
--
作者：
Grima, Ramon;Schnell, Santiago
要注意!非经典动力学的两种不同的理论描述：分形动力学（具有时间相关速率系数的动力学）和幂律近似（广义质量作用动力学）仅对具有相同初始浓度的A+A→ø orA+B→ø类型的简单反应证明是等效的。在所有其他情况下，它们是不一样的。
Take caution!The two distinct theoretical descriptions of non‐classical kinetics: fractal‐like kinetics (kinetics with time‐dependent rate coefficients) and the power law approximation (generalized mass action kinetics) are shown to be equivalent only for simple reactions of the typeA+A→ø orA+B→ø with equal initial concentrations ofAandB.In all other cases they are not the same.