Marine Atmospheric Corrosion of Carbon Steel: A Review.

Marine Atmospheric Corrosion of Carbon Steel: A Review.
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DOI:
10.3390/ma10040406
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发表时间:
2017-04-13
期刊:
Materials (Basel, Switzerland)
影响因子:
--
通讯作者:
Morcillo M
Morcillo M
中科院分区:
其他
文献类型:
--
作者:
Alcántara J;Fuente D;Chico B;Simancas J;Díaz I;Morcillo M

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碳钢的大气腐蚀是一个广泛的话题,多年来一直被许多研究人员研究。然而,直到最近,令人惊讶的是很少有人注意到海洋氯化物的作用。由于沿海地区对人类社会的重要性,沿海地区的腐蚀是一个特别相关的问题。世界上大约一半的人口生活在沿海地区,发展中国家的工业化倾向于将生产工厂集中在靠近海洋的地方。直到世纪初,对富氯大气中铁锈形成的基本机制的研究仅限于少数研究。然而,近年来,对海洋大气腐蚀的科学认识有了很大的进步,作者认为,在已发表的科学论文中已经建立了足够的知识体系,以保证对当前最新技术水平进行最新审查,并评估仍需解决的问题。这就是本次审查的目的。在介绍了大气腐蚀、海洋大气和海洋大气腐蚀实验的基本概念后,本文讨论了主要的腐蚀产物、形成的锈层特性和海洋大气中钢铁腐蚀的机制等关键问题。然后特别注意重要的问题,如沿海工业大气和碳钢暴露于海洋大气的长期行为。本书最后有一节专门讨论悬而未决的问题,指出似乎有必要加大研究力度的一系列问题。
The atmospheric corrosion of carbon steel is an extensive topic that has been studied over the years by many researchers. However, until relatively recently, surprisingly little attention has been paid to the action of marine chlorides. Corrosion in coastal regions is a particularly relevant issue due the latter’s great importance to human society. About half of the world’s population lives in coastal regions and the industrialisation of developing countries tends to concentrate production plants close to the sea. Until the start of the 21st century, research on the basic mechanisms of rust formation in Cl−-rich atmospheres was limited to just a small number of studies. However, in recent years, scientific understanding of marine atmospheric corrosion has advanced greatly, and in the authors’ opinion a sufficient body of knowledge has been built up in published scientific papers to warrant an up-to-date review of the current state-of-the-art and to assess what issues still need to be addressed. That is the purpose of the present review. After a preliminary section devoted to basic concepts on atmospheric corrosion, the marine atmosphere, and experimentation on marine atmospheric corrosion, the paper addresses key aspects such as the most significant corrosion products, the characteristics of the rust layers formed, and the mechanisms of steel corrosion in marine atmospheres. Special attention is then paid to important matters such as coastal-industrial atmospheres and long-term behaviour of carbon steel exposed to marine atmospheres. The work ends with a section dedicated to issues pending, noting a series of questions in relation with which greater research efforts would seem to be necessary.
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