Aerobic Oxidative Coupling of 2-Naphthol Derivatives Catalyzed by a Copper-Amine Complex without Solvent
Aerobic Oxidative Coupling of 2-Naphthol Derivatives Catalyzed by a Copper-Amine Complex without Solvent
复制标题
无溶剂铜胺配合物催化2-萘酚衍生物的有氧氧化偶联
DOI：
10.1248/cpb.46.1814
复制
发表时间：
1998
影响因子：
1.7
通讯作者：
K. Koga
中科院分区：
文献类型：
--
作者：
M. Nakajima;S. Hashimoto*;Masahiro Noji;K. Koga
研究发现，铜胺络合物催化的萘酚氧氧化偶联反应在无溶剂条件下进行，反应效率较高。将该反应应用于多克级1，1‘-联苯-2，2’-二醇的实际合成。
Aerobic oxidative coupling of naphthols catalyzed by a copper-amine complex was found to proceed without solvent in high efficacy. The present reaction was applied to a practical synthesis of 1, 1'-binaphthalene-2, 2'-diol on multi-gram scale.