Direct β-Selective Hydrocarboxylation of Styrenes with CO2 Enabled by Continuous Flow Photoredox Catalysis
Direct β-Selective Hydrocarboxylation of Styrenes with CO2 Enabled by Continuous Flow Photoredox Catalysis
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DOI：
10.1021/jacs.7b05942
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发表时间：
2017-10-11
影响因子：
15
通讯作者：
Jamison, Timothy F.
中科院分区：
文献类型：
--
作者：
Seo, Hyowon;Liu, Aofei;Jamison, Timothy F.
利用连续流动光氧化还原催化技术，研究了常压CO2条件下，苯乙烯类化合物的直接β-选择性氢化反应。这一方法的范围通过一系列功能化的末端苯乙烯以及α-取代和β-取代的苯乙烯来证明。
The direct beta-selective hydrocarboxylation of styrenes under atmospheric pressure of CO2 has been developed using photoredox catalysis in continuous flow. The scope of this methodology was demonstrated with a range of functionalized terminal styrenes, as well as alpha-substituted and beta-substituted styrenes.