Highly Efficient Generation of Ammonium Eneselenolates, Their Reactions and Electronic Properties

Highly Efficient Generation of Ammonium Eneselenolates, Their Reactions and Electronic Properties
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烯烯醇酸铵的高效生成及其反应和电子性质

DOI:
10.1246/cl.2000.368
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发表时间:
2000
期刊:
影响因子:
--
通讯作者:
S. Kato
S. Kato
中科院分区:
--
文献类型:
--
作者:
T. Murai;S. Hayakawa;S. Kato

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The ammonium eneselenolates generated from selenothioic acid S-esters and ammonium fluoride were reacted with carbon electrophiles to furnish ketene selenothioacetals with high stereoselectivities. The spectroscopic properties of the ammonium eneselenolates have suggested that the electrons on the selenium atom efficiently delocalize on the carbon-carbon double bond.