Polycyclic aromatic hydrocarbons in spanish olive oils: relationship between benzo(a)pyrene and total polycyclic aromatic hydrocarbon content.
Polycyclic aromatic hydrocarbons in spanish olive oils: relationship between benzo(a)pyrene and total polycyclic aromatic hydrocarbon content.
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DOI：
10.1021/jf8016699
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发表时间：
2008-11
影响因子：
6.1
通讯作者：
R. Rodríguez-Acuña;María del Carmen Pérez-Camino;A. Cert;W. Moreda
中科院分区：
文献类型：
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作者：
R. Rodríguez-Acuña;María del Carmen Pérez-Camino;A. Cert;W. Moreda
对不同类别、产地、品种和商业品牌的西班牙初榨橄榄油(VOO)样品进行了高效液相色谱分析，并用可编程荧光检测器测定了9种重多环芳烃(PAHs)的含量：苯并(A)菲、大黄烯、苯并(E)芘、苯并(B)荧菲、苯并(K)荧菲、苯并(A)芘、二苯并(a，h)菲、苯并(g，h，i)紫丁烯和吲哚(1，2，3-c，d)芘。还对橄榄渣和粗橄榄渣油的样品进行了调查。在97%的VOO样品中，苯并(A)芘的浓度低于欧盟允许的限量(2微克/公斤)。只有那些来自受污染的橄榄水果或在环境污染严重的油厂获得的样本超过了这一值。在所分析的所有类别中，苯并(A)芘的含量与9种多环芳烃的总和之间具有很高的相关性(<；0.99)，表明苯并(A)芘可以作为橄榄油中这9种多环芳烃含量的标志。
Samples of Spanish virgin olive oils (VOOs) from different categories, origins, varieties, and commercial brands were analyzed by HPLC with a programmable fluorescence detector to determine the content of nine heavy polycyclic aromatic hydrocarbons (PAHs): benzo(a)anthracene, chrysene, benzo(e)pyrene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(a)pyrene, dibenzo(a,h)anthracene, benzo(g,h,i)perilene, and indeno(1,2,3-c,d)pyrene. Samples of olive pomace and crude olive pomace oils were also investigated. Benzo(a)pyrene concentrations were below the allowed limit in the European Union (2 microg/kg) in 97% of the VOO samples. Only those samples coming from contaminated olive fruits or obtained in oil mills with highly polluted environments exceeded this value. High correlation coefficients (<0.99) were obtained between the contents of benzo(a)pyrene and the sum of the nine PAHs for all of the analyzed categories, suggesting that benzo(a)pyrene could be used as a marker of the content of these nine PAHs in olive oils.