Optically Transparent Thin Film of Layered Niobate (K4Nb6O17) Intercalated with Tris(2,2′-bipyridyl)ruthenium(II)
Optically Transparent Thin Film of Layered Niobate (K4Nb6O17) Intercalated with Tris(2,2′-bipyridyl)ruthenium(II)
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DOI：
10.1246/cl.2005.608
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发表时间：
2005-03
影响因子：
1.6
通讯作者：
Zhiwei Tong;S. Takagi;H. Tachibana;K. Takagi;H. Inoue
中科院分区：
文献类型：
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作者：
Zhiwei Tong;S. Takagi;H. Tachibana;K. Takagi;H. Inoue
采用一种独特的主客体离子交换方法制备了具有1）光学透明性和2）离子交换性的纳米层状K4Nb6O17.3H2O薄膜，这是此类材料的第一个实例。以插层化合物MV 2 +-K4 Nb 6 O 17为前驱体，采用主客体交换法成功制备了具有光响应性的Ru（bpy）32 +-K4 Nb 6 O 17杂化薄膜.
A unique guest-guest ion exchange method was developed for preparing a thin film of a nano-layered K 4 Nb 6 O 1 7 .3H 2 O that possesses both 1) optical transparency and 2) ion-exchangeability, the first example of such a material. An optically transparent Ru(bpy) 3 2 + -K 4 Nb 6 O 1 7 hybrid thin film, a potential photo-responsive electrode, was successfully prepared by the guest-guest exchange method by use of the intercalation compound MV 2 + -K 4 Nb 6 O 1 7 as a precursor.