A novel synthesis of trifluoromethyl ethers via xanthates, utilizing BrF3
A novel synthesis of trifluoromethyl ethers via xanthates, utilizing BrF3
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DOI：
10.1016/s0022-1139(99)00031-7
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发表时间：
1999-07-20
影响因子：
1.9
通讯作者：
Rozen, S
中科院分区：
文献类型：
--
作者：
Ben-David, I;Rechavi, D;Rozen, S
醇类转化为三氟甲基醚的方法是将其转化为黄原酸酯，几乎是定量的，然后与三氟化溴反应，三氟化溴是一种很少用于有机化学的试剂。(C)1999年Elsevier Science S.A. All rights reserved.
Alcohols were transformed into trifluoromethyl ethers by converting them to xanthates in almost quantitative yields followed by a reaction with bromine trifluoride, a reagent rarely used in organic chemistry. (C) 1999 Elsevier Science S.A. All rights reserved.