A new route to biphenylene via Vollhardt cyclization from o-bis[(trimethylsilyl)ethynyl]benzene
A new route to biphenylene via Vollhardt cyclization from o-bis[(trimethylsilyl)ethynyl]benzene
复制标题
邻双[(三甲基硅基)乙炔基]苯通过Vollhardt环化制备联苯的新路线
DOI：
10.1021/jo00137a040
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发表时间：
1982
期刊：
影响因子：
--
通讯作者：
E. Gesing
中科院分区：
文献类型：
--
作者：
E. Gesing
描述了邻双[(三甲基硅基)乙炔基)]-苯与环戊二烯基二羰基钴作为催化剂和试剂的反应，分别产生联亚苯基衍生物和带有新型有机配体的钴配合物。先生：在过去的十年中，钴催化的分子内和分子间乙炔和烯烃共聚已经得到了深入研究，1, 2产生了许多天然产物产品1 23 和理论上感兴趣的物种。然而，4 3-己烯-1, 5-二炔衍生物迄今为止尚未发挥作用，尽管可能会合成有趣的应变分子。
Reaction of o-bis [(trimethylsilyl) ethynyl)]-benzene with cyclopentadienyldicarbonylcobalt as catalyst and reagent is described, yielding biphenylene derivatives and cobalt complexes bearing novel organic ligands, re-spectively.Sir: In the last decade, cobalt-catalyzed intra-and intermolecular acetylene and olefin cooligomerizationshave been investigated intensively, 1, 2 yielding a number of natural products1 23 and species of theoretical interest. 4 3-Hexene-l, 5-diyne derivatives, however, have not played a role, hitherto, although interesting strained molecules might be synthesized.