Production of linear alkane via hydrogenative ring opening of a furfural-derived compound in supercritical carbon dioxide
Production of linear alkane via hydrogenative ring opening of a furfural-derived compound in supercritical carbon dioxide
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DOI：
10.1039/b919810p
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发表时间：
2010-05
期刊：
影响因子：
9.8
通讯作者：
M. Chatterjee;Keichiro Matsushima;Y. Ikushima;Masahiro Sato;T. Yokoyama;H. Kawanami;Suzuki Toshishige-
中科院分区：
文献类型：
--
作者：
M. Chatterjee;Keichiro Matsushima;Y. Ikushima;Masahiro Sato;T. Yokoyama;H. Kawanami;Suzuki Toshishige-
描述了一种简单的方法，可在非常温和的条件下使用 Pd/Al-MCM-41 催化剂在超临界二氧化碳中形成选择性 >99% 的直链烷烃。直链烷烃是由5-羟甲基糠醛与丙酮的醇醛缩合产物4-5-(5-(羟甲基)呋喃-2-基)丁-3-烯-2-酮经加氢、脱水/加氢形成。
A simple method has been described to accomplish the formation of linear alkane with >99% selectivity in supercritical carbon dioxide under very mild conditions using Pd/Al-MCM-41 catalyst. The linear alakne was formed through the hydrogenation and dehydration/hydrogenation of 4-5-(5-(hydroxymethyl)furan-2-yl)but-3-en-2-one, which is an aldol condensation product of 5-hydroxymethyl furfural and acetone.