ANTIFERROMAGNETIC RESONANCE AS A TOOL FOR INVESTIGATING MAGNETOSTRUCTURAL CORRELATIONS : THE CANTED ANTIFERROMAGNETIC STATE OF KMNPO4.H2O AND A SERIES OF MANGANESE PHOSPHONATES
ANTIFERROMAGNETIC RESONANCE AS A TOOL FOR INVESTIGATING MAGNETOSTRUCTURAL CORRELATIONS : THE CANTED ANTIFERROMAGNETIC STATE OF KMNPO4.H2O AND A SERIES OF MANGANESE PHOSPHONATES
复制标题
DOI：
10.1021/ja974247g
复制
发表时间：
1998-05
影响因子：
15
通讯作者：
G. Fanucci;J. Krzystek;M. Meisel;L. Brunel;D. Talham
中科院分区：
文献类型：
--
作者：
G. Fanucci;J. Krzystek;M. Meisel;L. Brunel;D. Talham
反铁磁共振（AFMR）被用来表征倾斜的反铁磁态，并探测一系列层状固体中的磁结构相关性，包括KMnPO 4·H2O、四种烷基膦酸锰、Mn（O3 PCnH 2n +1）·H2O（n = 3−6）和苯基膦酸锰。所有样品均作为粉末进行研究。一套完整的磁性参数，确定从AFMR和SQUID磁强计，为每种材料。使用位于佛罗里达塔拉哈西的国家高磁场实验室的高场电子磁共振设备获取AFMR谱。源频率范围为24至380 GHz，磁场范围为0 - 14.5 T。的磁交换和电子结构的桥接配体以及测量的磁各向异性的有序状态之间的相关性确定从分析的频率和场的依赖性的AFMR信号。
Antiferromagnetic resonance (AFMR) is used to characterize the canted antiferromagnetic state and to probe magnetostructural correlations within a series of layered solids including KMnPO4·H2O, four manganese alkylphosphonates, Mn(O3PCnH2n+1)·H2O (n = 3−6), and manganese phenylphosphonate. All samples were investigated as powders. A complete set of magnetic parameters, determined from AFMR and SQUID magnetometry, are presented for each material. The high field electron magnetic resonance facility at the National High Magnetic Field Laboratory in Tallahassee, Florida, was used to acquire AFMR spectra. Source frequencies ranged from 24 to 380 GHz, and the magnetic field range was 0−14.5 T. Correlations between the magnetic exchange and the electronic structure of the bridging ligand as well as measurements of the magnetic anisotropy in the ordered state are determined from analysis of the frequency and field dependence of the AFMR signals.