Applications of Ferrocenium Salts in Organic Synthesis
Applications of Ferrocenium Salts in Organic Synthesis
复制标题
二茂铁盐在有机合成中的应用
DOI：
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发表时间：
2015
期刊：
影响因子：
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通讯作者：
R. Šebesta
中科院分区：
文献类型：
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作者：
Š. Tomá;R. Šebesta
摘要二茂铁可通过人工合成或原位反应制备二茂铁盐。二茂铁离子可以作为单电子氧化剂，从而引发或促进一系列自由基过程。二茂铁本身可以向合适的底物提供电子，从而产生有用的转化。二茂铁盐也可以作为温和的路易斯酸。本文重点介绍了二茂铁离子在有机反应中的各种用途。2二茂铁盐作为路易斯酸3二茂铁盐作为单电子氧化剂4二茂铁作为电子供体5其他二茂铁衍生物的催化作用6结论
Abstract Ferrocenium salts can be easily obtained from ferrocene by either synthetic preparation or in situ reaction. The ferrocenium ion can act as a one-electron oxidant and thus initiate or promote a range of radical processes. Ferrocene itself can donate electrons to suitable substrates, resulting in useful transformations. Ferrocenium salts can also act as mild Lewis acids. This paper highlights various uses of ferrocenium ions in organic reactions. 1 Introduction 2 Ferrocenium Salts as Lewis Acids 3 Ferrocenium Salts as One-Electron Oxidants 4 Ferrocene as an Electron Donor 5 Catalysis with Other Ferrocenium Derivatives 6 Conclusions