Submillimeter-wave spectroscopy of HCNH+ and CH3CNH+

Submillimeter-wave spectroscopy of HCNH+ and CH3CNH+
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DOI:
10.1016/j.molstruc.2006.02.035
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发表时间:
2006-08-21
影响因子:
3.8
通讯作者:
Hirao, T.
Hirao, T.
中科院分区:
化学2区
文献类型:
--
作者:
Amano, T.;Hashimoto, K.;Hirao, T.

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HCNH+和CH3CNH+的纯旋转跃迁在750ghz和3cnh +的325- 500ghz范围内进行了测量。所提出的HCNH+的分子常数比先前确定的值有了明显的改善。首次观测到CH3CNH+的亚毫米波线,与红外测量相比,分子常数的精度得到了提高。(c) 2006 Elsevier B.V.版权所有
The pure rotational transitions of HCNH+ and CH3CNH+ have been measured up to 750 GHz for HCNH+ and in the range of 325-500 GHz for CH3CNH+. The presented molecular constants of HCNH+ are a definite improvement over previously determined values. Submillimeter-wave lines for CH3CNH+ have been observed for the first time and the accuracy of the molecular constants has been improved, compared with that attained by infrared measurements. (c) 2006 Elsevier B.V. All rights reserved.