Carboxylation of dihydroxoplatinum(IV) complexes with acyl chlorides. Crystal structures of the trans-R,R- and trans-S,S-isomer of (OC-6-33)-bis(1-adamantanecarboxylato)-(cyclohexane-1,2-diamine)dichloroplatinum(IV)
Carboxylation of dihydroxoplatinum(IV) complexes with acyl chlorides. Crystal structures of the trans-R,R- and trans-S,S-isomer of (OC-6-33)-bis(1-adamantanecarboxylato)-(cyclohexane-1,2-diamine)dichloroplatinum(IV)
复制标题
DOI：
10.1016/s0020-1693(97)05639-9
复制
发表时间：
1997-11-15
影响因子：
2.8
通讯作者：
Keppler, BK
中科院分区：
文献类型：
--
作者：
Galanski, MS;Keppler, BK
合成无机化学最近利用羟基金属配合物的亲核特性来合成羧基金属化合物。描述了酰氯对二羟基铂（IV）化合物的羧化，这是一种利用经典有机羧化剂的无机化学方法。通过氢氧化物与铂(IV)配位的酰化合成了(OC-6-33)-双(1-金刚烷-羧基)(环己烷-1,2-二胺)二氯铂(IV)的反式-R,R-和反式-S,S-异构体，通过元素分析、红外光谱和核磁共振表征，并解析了晶体结构。 (C) 1997 Elsevier Science S.A.
Synthetic inorganic chemistry recently has made use of the nucleophilic properties of hydroxo metal complexes to synthesize carboxylato metal compounds. The carboxylation of dihydroxoplatinum(IV) compounds by acyl chlorides is described, a method in inorganic chemistry which makes use of the classical organic carboxylation agent. The trans-R,R- and trans-S,S-isomers of (OC-6-33)-bis(1-adamantane-carboxylato)(cyclohexane-1,2-diamine)dichloroplatinum(IV) were synthesized by acylation of hydroxide coordinated to platinum(IV), characterized by elemental analysis as well as IR and NMR spectroscopy, and the crystal structures were resolved. (C) 1997 Elsevier Science S.A.