Indium(III) Isopropoxide as a Hydrogen Transfer Catalyst for Conversion of Benzylic Alcohols into Aldehydes or Ketones via Oppenauer Oxidation

Indium(III) Isopropoxide as a Hydrogen Transfer Catalyst for Conversion of Benzylic Alcohols into Aldehydes or Ketones via Oppenauer Oxidation
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DOI：
10.1055/s-0035-1562542
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发表时间：
2016-09
期刊：
Synthesis
影响因子：
--
通讯作者：
Yohei Ogiwara;Yuji Ono;Norio Sakai
Yohei Ogiwara;Yuji Ono;Norio Sakai
中科院分区：
其他
文献类型：
--
作者：
Yohei Ogiwara;Yuji Ono;Norio Sakai

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摘要 异丙醇铟[In(Oi-Pr)3]可作为奥本诺氧化催化剂，以新戊醛为氧化剂，在室温下促进伯醇或仲醇转化为相应的醛或酮。
Abstract Indium(III) isopropoxide [In(Oi-Pr)3] was applicable as an Oppenauer oxidation catalyst, and the conversion of primary or secondary alcohols into the corresponding aldehydes or ketones was promoted at room temperature using pivalaldehyde as an oxidant.