Association behaviors of poly(N-vinylpyrrolidone)-grafted fullerenes in aqueous solution
Association behaviors of poly(N-vinylpyrrolidone)-grafted fullerenes in aqueous solution
复制标题
聚(N-乙烯基吡咯烷酮)接枝富勒烯在水溶液中的缔合行为
DOI:
10.1007/s10965-018-1604-5
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发表时间:
2018
影响因子:
2.8
通讯作者:
Sanami Moroi
中科院分区:
文献类型:
--
作者:
Emiko Mouri;Sanami Moroi
Poly(N-vinylpyrrolidone) (PVP)-grafted fullerenes (PVP-C60and PVP-C70) were synthesized by iniferter polymerization in order to fabricate water-soluble fullerene containing micelles. PVP-C60formed micelles with hydrodynamic diameters ranging from 15 to 33 nm. The solubilization of fullerene molecules into the core of the PVP-C60micelles was also found to control the size of the micelles. By increasing the amount of added fullerene, we gradually increased the micelle size before drastically increasing it to that of 200 nm in hydrodynamic diameter. The drastic change occurred at a critical value of the added C60/PVP monomer ratio, almost independently of the molecular weight of PVP.
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