Organometallic molecular wires and other nanoscale-sized devices: An approach using the organoiron (dppe)Cp*Fe building block
Organometallic molecular wires and other nanoscale-sized devices: An approach using the organoiron (dppe)Cp*Fe building block
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DOI：
10.1016/s0010-8545(98)00150-7
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发表时间：
1998-12
影响因子：
20.6
通讯作者：
F. Paul;C. Lapinte
中科院分区：
文献类型：
--
作者：
F. Paul;C. Lapinte
本文讨论了由两个过渡金属中心由有机不饱和间隔层连接而成的有机金属结构在研究和开发新型分子线方面的潜力。在对具有代表性的现有分子进行书目调查后，重点放在末端有机金属盖层基团的决定性作用上。在这方面，随后发展了单核配合物中（dppe）Cp*Fe单元的非常丰富的氧化还原化学。最后，介绍了本小组实现的各种有机金属分子线模型的合成和研究，并对目前的技术状况进行了总结。一篇有352篇参考文献的综述。
In this paper, the potential that organometallic architectures consisting of two transition metal centers linked by an organic unsaturated spacer present for the study and development of new molecular wires is discussed. After a bibliographical survey of representative existing molecules, emphasis is set on the decisive role of the terminal organometallic capping groups. In this connection, the very rich redox chemistry of the (dppe)Cp*Fe unit in mononuclear complexes is subsequently developed. Finally, the syntheses and studies of diverse organometallic molecular wire models realized in our group and incorporating this fragment are presented and conclusions on the present state of the art are drawn. A review with 352 references.