3',4-DI-O-METHYLCEDRUSIN - SYNTHESIS, RESOLUTION AND ABSOLUTE-CONFIGURATION
3',4-DI-O-METHYLCEDRUSIN - SYNTHESIS, RESOLUTION AND ABSOLUTE-CONFIGURATION
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DOI：
10.1039/p19950001775
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发表时间：
1995-07-07
期刊：
影响因子：
--
通讯作者：
BUSS, V
中科院分区：
文献类型：
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作者：
LEMIERE, G;GAO, M;BUSS, V
标题化合物已合成的外消旋形式的仿生反应序列。通过其中一种合成中间体的柱层析分离两种对映体。根据圆二色性计算结果，提出了合成的对映体和天然3 ′，4-二-O-甲基柏木素的绝对构型。
The title compound has been synthesised in racemic form by a biomimetic reaction sequence. The two enantiomers were resolved by column chromatography of one of the synthetic intermediates. On the basis of CD results a tentative absolute configuration for the synthetic enantiomers and natural 3',4-di-O-methylcedrusin is proposed.