Radical reactions in aqueous medium using (Me3Si)3SiH
Radical reactions in aqueous medium using (Me3Si)3SiH
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DOI：
10.1021/ol7020803
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发表时间：
2007-12-06
期刊：
影响因子：
5.2
通讯作者：
Chatgilialoglu, Chryssostornos
中科院分区：
文献类型：
--
作者：
Postigo, Al;Kopsov, Sergey;Chatgilialoglu, Chryssostornos
(Me3Si)(3)SiH was used as a successful reagent in a variety of radical-based transformations in water. The system comprising substrate, silane, and initiator (ACCN) mixed in aqueous medium at 100 degrees C worked well for both hydrophilic and hydrophobic substrates, with the only variation that an amphiphilic thiol was also needed in case of the water-soluble compounds.
