End-functional stereoregular poly(methyl methacrylate) with clickable C=C bonds: facile synthesis and thiol-ene reaction
End-functional stereoregular poly(methyl methacrylate) with clickable C=C bonds: facile synthesis and thiol-ene reaction
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具有可点击C=C键的末端功能性立构规整聚（甲基丙烯酸甲酯）：易于合成和硫醇-烯反应
DOI：
10.1039/c3py00799e
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发表时间：
2013
影响因子：
4.6
通讯作者：
Takashi Kurata and Tatsuki Kitayama
中科院分区：
文献类型：
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作者：
Yasuhiro Kohsaka;Takashi Kurata and Tatsuki Kitayama
通过与α-(卤甲基)丙烯酸酯的阴离子封端反应，通过迈克尔加成型硫醇-烯反应合成了具有可点击CC ω-末端的立构规整聚(甲基丙烯酸甲酯)。 ω末端的硫醇-烯点击反应定量地提供了各种ω官能聚合物。
Stereoregular poly(methyl methacrylate) with a clickable CC ω-end by a Michael-addition type thiol–ene reaction was synthesized through an anion terminating reaction with α-(halomethyl)acrylates. The thiol–ene click reaction at the ω-end provided various ω-functional polymers quantitatively.