Metal carbonate complexes formed through the capture of ambient O2 and CO2 by elemental metals in 1-methylimidazole: molecular Cu(CO3)(MeIm)3 and polymeric M(CO3)(MeIm)2·2H2O (M = Co, Zn).

Metal carbonate complexes formed through the capture of ambient O2 and CO2 by elemental metals in 1-methylimidazole: molecular Cu(CO3)(MeIm)3 and polymeric M(CO3)(MeIm)2·2H2O (M = Co, Zn).
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DOI:
10.1039/c7dt01787a
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发表时间:
2017-07
影响因子:
4
通讯作者:
T. Vaid;Steven P. Kelley;R. Rogers
T. Vaid;Steven P. Kelley;R. Rogers
中科院分区:
化学2区
文献类型:
--
作者:
T. Vaid;Steven P. Kelley;R. Rogers

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当浸入1-甲基咪唑中时,金属铜、锌和钴将与环境中的氧气和二氧化碳反应,分别产生蓝绿色分子络合物Cu(CO 3)(MeIm)3和一对同构聚合物络合物Zn(CO 3)(MeIm)2·2 H2O和Co(CO 3)(MeIm)2·2 H2O。
When immersed in 1-methylimidazole, the metals copper, zinc, and cobalt will react with ambient dioxygen and carbon dioxide to yield the blue-green molecular complex Cu(CO3)(MeIm)3 and the pair of isostructural polymeric complexes Zn(CO3)(MeIm)2·2H2O and Co(CO3)(MeIm)2·2H2O, respectively.