Simple Treatment of the Symmetry Labels for the d-d States of Octahedral Complexes
Simple Treatment of the Symmetry Labels for the d-d States of Octahedral Complexes
复制标题
八面体配合物d-d态对称标号的简单处理
DOI：
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发表时间：
1996
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通讯作者：
Derek W. Smith
中科院分区：
文献类型：
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作者：
Derek W. Smith
对于具有群论基础知识的学生来说，d块元素的立方（八面体和四面体）复合体的d-d态的对称性标签的推导并不容易理解。本文给出了八面体d^n复体（在点群O中）的d-d态是如何通过对称性下降到D2来计算的，并使用相应的特征标表和乘法表来表示它们的不可约表示。
The derivation of the symmetry labels for d-d states of cubic (octahedral and tetrahedral) complexes of d block elements is not readily accessible to students having an elementary knowledge of group theory. This paper shows how the d-d states of octahedral d^n complexes (in the point group O) can be worked out by descent in symmetry to D2, using the relevant character tables and multiplication tables for their irreducible representations.