Room temperature multiferroic properties of (Bi0.95La0.05)(Fe0.97Mn0.03)O3/NiFe2O4 double layered thin film

Room temperature multiferroic properties of (Bi0.95La0.05)(Fe0.97Mn0.03)O3/NiFe2O4 double layered thin film
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DOI:
10.1016/j.materresbull.2013.08.001
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发表时间:
2013-11
影响因子:
5.4
通讯作者:
C. M. Raghavan;H. Kim;J. Kim;S. S. Kim-S.
C. M. Raghavan;H. Kim;J. Kim;S. S. Kim-S.
中科院分区:
材料科学2区
文献类型:
--
作者:
C. M. Raghavan;H. Kim;J. Kim;S. S. Kim-S.

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采用化学溶液沉积法在Pt(111)/Ti/SiO2/Si(100)衬底上制备了(Bi0.95La0.05)(Fe0.97Mn0.03)O3/NiFe 2 O 4双层薄膜。X射线衍射和拉曼散射光谱研究证实了(Bi 0.95 La 0.05)(Fe 0.97 Mn 0.03)O3/NiFe 2 O 4双层薄膜的畸变菱面体钙钛矿和反尖晶石立方结构的形成。的(Bi0.95La0.05)(Fe0.97Mn0.03)O3/NiFe 2 O 4双层薄膜具有良好的饱和铁磁性能(20 kOe时的2 Mr为18.1 emu/cm ~ 3,2 Hc为0.32 kOe)和铁电体(2 Prof 60 μC/cm 2和2 Ecof 813 kV/cm,866 kV/cm)具有低阶漏电流密度的磁滞回线(在100 kV/cm的外加电场下为4.5 × 10−6A/cm 2),这表明了铁电和铁磁多层膜在真实的器件中的应用。
(Bi0.95La0.05)(Fe0.97Mn0.03)O3/NiFe2O4double layered thin film was prepared on a Pt(111)/Ti/SiO2/Si(100) substrate by a chemical solution deposition method. X-ray diffraction and Raman scattering spectroscopy studies confirmed the formation of the distorted rhombohedral perovskite and the inverse spinel cubic structures for the (Bi0.95La0.05)(Fe0.97Mn0.03)O3/NiFe2O4double layered thin film. The (Bi0.95La0.05)(Fe0.97Mn0.03)O3/NiFe2O4double layered thin film exhibited well saturated ferromagnetic (2Mrof 18.1 emu/cm3and 2Hcof 0.32 kOe at 20 kOe) and ferroelectric (2Prof 60 μC/cm2and 2Ecof 813 kV/cm at 866 kV/cm) hysteresis loops with low order of leakage current density (4.5 × 10−6A/cm2at an applied electric field of 100 kV/cm), which suggest the ferroelectric and ferromagnetic multi-layers applications in real devices.