1-(3-Chloro-4-fluoro-phen-yl)-5-(2-diazo-acet-yl)-4-phenyl-pyrrolidin-2-one.
1-(3-Chloro-4-fluoro-phen-yl)-5-(2-diazo-acet-yl)-4-phenyl-pyrrolidin-2-one.
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1-(3-氯-4-氟-苯基-基)-5-(2-重氮-乙酰基)-4-苯基-吡咯烷-2-酮。
DOI：
10.1107/s1600536810024657
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发表时间：
2010
期刊：
影响因子：
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通讯作者：
Santaballa,JA
中科院分区：
文献类型：
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作者：
Ray,JayantaKumar;Haldar,Pranab;CanleL,M;FernándezP,MI;Santaballa,JA
在标题化合物 C18H13ClFN3O2 中，吡咯烷环采用包络构象，平面部分从苯环平面旋转 4.3 (6)°，几乎垂直于重氮乙酰基单元 [二面角 = 78.93 (7)°] 和苯环 [二面角 = 86.07 (7)°]。在晶体中，分子通过 C—H⋯O 相互作用连接成三维框架。分子构象通过分子内C—H⋯O氢键稳定。
In the title compound, C18H13ClFN3O2, the pyrrolidine ring adopts an envelope conformation and the planar part is rotated by 4.3 (6)° from the plane of the benzene ring and is almost perperdicular both to the diazoacetyl unit [dihedral angle = 78.93 (7)°] and the phenyl ring [dihedral angle = 86.07 (7)°]. In the crystal, molecules are linked into a three-dimensional framework by C—H⋯O interactions. The molecular conformation is stabilized by an intramolecular C—H⋯O hydrogen bond.