The variations in hydrogen bonding in hexafluorosilicate salts of protonated methyl substituted pyridines and tetramethylethylenediamine
The variations in hydrogen bonding in hexafluorosilicate salts of protonated methyl substituted pyridines and tetramethylethylenediamine
复制标题
质子化甲基取代吡啶和四甲基乙二胺的六氟硅酸盐中氢键的变化
DOI：
10.1016/j.jfluchem.2008.06.022
复制
发表时间：
2008
影响因子：
1.9
通讯作者：
A. Demšar
中科院分区：
文献类型：
--
作者：
Andrej Pevec;A. Demšar
The synthesis and spectroscopic characterization of hexafluorosilicate salts with organic cations (R)2[SiF6] (where R=2-picolinium (1), 2,6-lutidinium (2) and 2,4,6-collidinium (3)) and R[SiF6]·2H2O (where R=tetramethylethylenediammonium (4)) are reported. The salts were prepared by the reaction of methyl substituted pyridines or tetramethylethylenediamine with hydrogen fluoride solution and subsequent addition of silica. The crystal structures of 1, 2 and 4 have been determined by single-crystal X-ray diffraction analysis. The effect of hydrogen bonding on the elongation of the SiF bonds is discussed.
影响因子：
4.9
作者：
Anderson, Kirsty M.;Goeta, Andres E.;Steed, Jonathan W.
通讯作者：
Steed, Jonathan W.