[18]Annulene put into a new perspective.
[18]Annulene put into a new perspective.
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[18]Annulene 提出了新的视角。
作者：
Dominik Lungerich;A. Nizovtsev;F. Heinemann;F. Hampel;K. Meyer;G. Majetich;P. Schleyer;N. Jux
通过更仔细地观察[18]轮烯的X射线结构，发现其在人字形晶体堆积中紧密地面对面堆积，从而获得了对[18]轮烯的新见解。六氢[18]轮烯在苯基质中共结晶，证明了插层溶剂分子在固体环烯中的稳定作用。
New insights into [18]annulene were gained by looking more closely at its X-ray structure, revealing a close face-to-face stacking of 3.16 Å in a herringbone-like crystal packing. Hexadehydro[18]annulene was co-crystalized in a benzene matrix, demonstrating the stabilizing role of intercalated solvent molecules in solid annulenes.