Di-2-pyridyl ketone/benzoate/azide combination as a source of copper(II) clusters and coordination polymers: dependence of the product identity on the solvent.
Di-2-pyridyl ketone/benzoate/azide combination as a source of copper(II) clusters and coordination polymers: dependence of the product identity on the solvent.
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DOI：
10.1021/ic801196u
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发表时间：
2008-09
影响因子：
4.6
通讯作者：
T. Stamatatos;V. Tangoulis;C. Raptopoulou;A. Terzis;Giannis S. Papaefstathiou;S. Perlepes
中科院分区：
文献类型：
--
作者：
T. Stamatatos;V. Tangoulis;C. Raptopoulou;A. Terzis;Giannis S. Papaefstathiou;S. Perlepes
The reactions of di-2-pyridyl ketone with Cu(O2CPh)2 in the presence of NaN3 and LiOH have led to an antiferromagnetically coupled (S = 0) Cu(II)6 cluster with a novel core and to (Cu(II)8)n and (Cu(II)2)n coordination polymers (the former 1D and the latter 2D) with interesting structures. The cluster or polymer formation depends on the reaction solvent.
