Synthesis and inversion barriers of undeca- and dodeca-substituted saddle shaped porphyrin complexes
Synthesis and inversion barriers of undeca- and dodeca-substituted saddle shaped porphyrin complexes
复制标题
DOI：
10.1016/j.tetlet.2005.05.100
复制
发表时间：
2005-07-25
影响因子：
1.8
通讯作者：
Nakamura, M
中科院分区：
文献类型：
--
作者：
Hoshino, A;Ohgo, Y;Nakamura, M
报道了一系列高鞍形配合物的合成及其反转势垒。在243 K下，当内消旋苯基被体积更大的2，6-二氯苯基取代时，Δ G（不相等）降低了8 kJ mol（-1），当去除一个外围乙基时，Δ G降低了17 kJ mol（-1）。(c)2005年由Elsevier Ltd.出版
Synthesis and barriers to inversion of a series of highly saddle shaped complexes are reported. The Delta G(not equal) has decreased by 8 kJ mol(-1) at 243 K when the meso phenyl groups are replaced by bulkier 2,6-dichlorophenyl groups, and by 17 kJ mol(-1) when one of the peripheral ethyl groups is removed. (c) 2005 Published by Elsevier Ltd.