A large-surface-area TS-1 nanocatalyst: a combination of nanoscale particle sizes and hierarchical micro/mesoporous structures.
A large-surface-area TS-1 nanocatalyst: a combination of nanoscale particle sizes and hierarchical micro/mesoporous structures.
复制标题
大表面积TS-1纳米催化剂：纳米级粒径和分级微/介孔结构的组合
作者：
By a simple sequent process of dry-gel steam-assisted crystallization and following a top-down alkali-etching treatment, hierarchically structured TS-1 nanozeolites (nanoTS-1_D) with abundant micro/mesopores have been synthesized for the first time, and they exhibit remarkably high specific surface area of 606 m2 g−1 and pore volume of 0.86 cm3 g−1. Characterization by XRD, FTIR, UV-vis and EM confirm the exclusive incorporation of titanium species in zeolite frameworks. More importantly, compared with the microporous TS-1 nanocrystal material with identical particle sizes of 80 nm (nanoTS-1) and submicrometer-sized mesoporous TS-1 material (mesoTS-1), here the reported nanoTS-1_D catalyst shows greatly improved performance in the model reaction of 1-hexene epoxidation. 40.9% olefin conversion and 96.3% epoxide selectivity are achieved and its high stability is verified by the 6 recycling–regeneration tests.
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影响因子：
7.3
作者：
Cheneviere, Yohan;Chieux, Frederic;Tuel, Alain
通讯作者：
Tuel, Alain
纳米晶和分级结构 TS-1 沸石的亲水/疏水调制合成
影响因子：
3.1
作者：
Ge, Tongguang;Hua, Zile;Shi, Jianlin
通讯作者：
Shi, Jianlin
影响因子：
7.3
作者：
Kumar, Anuj;Srinivas, Darbha
通讯作者：
Srinivas, Darbha
影响因子：
7.3
作者：
Tarach, Karolina A.;Martinez-Triguero, Joaquin;Gora-Marek, Kinga
通讯作者：
Gora-Marek, Kinga
影响因子：
8.4
作者：
Martínez-Franco R;Paris C;Martínez-Armero ME;Martínez C;Moliner M;Corma A
通讯作者：
Corma A