Hybridization of Clay Minerals with the Floating Film of a Cationic Ir(III) Complex at an Air-water Interface
Hybridization of Clay Minerals with the Floating Film of a Cationic Ir(III) Complex at an Air-water Interface
复制标题
粘土矿物与阳离子 Ir(III) 络合物浮膜在空气-水界面的杂化
DOI：
10.1039/c0nj00534g
复制
发表时间：
2011
影响因子：
3.3
通讯作者：
A. Yamagishi
中科院分区：
文献类型：
--
作者：
H. Sato;K. Tamura;K. Ohara;S. Nagaoka;A. Yamagishi
将粘土矿物(合成皂石、合成钠蒙脱石和钠基蒙脱石)与阳离子Ir(III)络合物[Ir(Ppy)2(Dc18bpy)]+(ppy=2-苯基吡啶；dc18bpy=4，4‘-二十八烷基-2，2’-联吡啶)的浮膜杂化，制备了Langmuir-Blodgett膜。当单层杂化LB膜在430 nm处被照射时，它在可见光区域发光，其强度对氧气压力的变化做出可逆的响应。
The Langmuir–Blodgett films were prepared by hybridizing the clay minerals (synthetic saponite, synthetic hectorite and sodium montmorillonite) with the floating film of a cationic Ir(III) complex, [Ir(ppy)2(dc18bpy)]+ (ppy = 2-phenylpyridine; dc18bpy = 4,4′-dioctadecyl-2,2′-bipyridine). When the single-layered hybrid LB film was irradiated at 430 nm, it emitted light in the visible region, whose intensity responded reversibly to the pressure change of oxygen.