Suppression of Schlenk Equilibration and Heavier Alkaline Earth Alkyl Catalysis: A Dearomatization Strategy
Suppression of Schlenk Equilibration and Heavier Alkaline Earth Alkyl Catalysis: A Dearomatization Strategy
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DOI：
10.1021/om200028m
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发表时间：
2011-03-28
期刊：
影响因子：
2.8
通讯作者：
Kociok-Koehn, Gabriele
中科院分区：
文献类型：
--
作者：
Arrowsmitla, Merle;Hill, Michael S.;Kociok-Koehn, Gabriele
Reaction of a bis(imino)acenapthene with the heavier alkaline earth dialkyls [Ae{CH(SiMe3)(2)}(2)(THF)(2)] (Ac = Mg, Ca, Sr) results in deromatization of the aromatic ligand and the isolation of heteroleptic alkyl species which show unprecedented stability toward Schlenk-type redistribution and exceptional catalytic activity toward the hydroamination of aminoalkeries.
