Synthesis and Structure of the Cadmium (II) Complex: [Cd(C5H5N)2(S2CO-n-C4H9)2]

Synthesis and Structure of the Cadmium (II) Complex: [Cd(C5H5N)2(S2CO-n-C4H9)2]
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DOI:
10.3390/70700549
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发表时间:
2002-07-31
期刊:
Molecules : A Journal of Synthetic Chemistry and Natural Product Chemistry
影响因子:
--
通讯作者:
Wang SL
Wang SL
中科院分区:
其他
文献类型:
--
作者:
Jiang XH;Zhang WG;Zhong Y;Wang SL

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合成了吡啶与[Cd(S2CO-n-C4H9)2]n的[Cd(C5H5N)2(S2CO-n-C4H9)2]加合物,并通过IR、元素分析、1H-NMR和X射线衍射分析进行了表征。该晶体属于单斜晶系,空间群P2(1)/c,Z=2。电池尺寸为a=1.1094(12)、b=0.6152(6)、c=1.7985(19) nm、•=96.148(2)°、V=1.2204(2)nm3。对于 I>2·(I) 的 2624 次反射,结构被细化为 R=0.0246 和 wR=0.0645。该配合物具有中心对称的分子结构。
The [Cd(C5H5N)2(S2CO-n-C4H9)2] adduct of pyridine with [Cd(S2CO-n-C4H9)2]n was synthesized and characterized by IR, elemental analysis, 1H-NMR and X-ray diffraction analysis. The crystasl belong to the monoclinic system, space group P2(1)/c with Z=2. Cell dimensions are a=1.1094(12), b=0.6152(6), c=1.7985(19) nm, • =96.148(2)°, V=1.2204(2)nm3. The tructure was refined to R=0.0246 and wR=0.0645 for 2624 reflections with I>2•(I). The complex has a centrosymmetric molecule structure.
DOI: 10.1016/s0020-1693(00)87575-1
发表时间: 1985-01-01
期刊: INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS
影响因子: --
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