The biosynthesis of sorbicillinoids in Trichoderma sp USF-2690:: prospect for the existence of a common precursor to sorbicillinol and 5-epihydroxyvertinolide, a new sorbicillinoid member
The biosynthesis of sorbicillinoids in Trichoderma sp USF-2690:: prospect for the existence of a common precursor to sorbicillinol and 5-epihydroxyvertinolide, a new sorbicillinoid member
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DOI：
10.1016/j.tetlet.2007.11.121
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发表时间：
2008-01-21
影响因子：
1.8
通讯作者：
Abe, Naoki
中科院分区：
文献类型：
--
作者：
Sugaya, Kouichi;Koshino, Hiroyuki;Abe, Naoki
对[1-C-13]、[2-C-13]和[1，2-C-13（2）]标记的乙酸钠合成5-表羟基维替尼（一种新的山梨西林）的生物合成补料研究，给出了一种掺入模式，证明了与前体（山梨西林醇生物合成的潜在中间体）的环裂解反应相关的γ-内酯环形成。(c)2007爱思唯尔有限公司保留所有权利。
Biosynthetic feeding studies of [1-C-13], [2-C-13], and [1,2-C-13(2)]-labeled sodium acetates into 5-epihydroxyvertinolide, a new sorbicillinoid, gives an incorporation pattern that proves the gamma-lactone ring formation associated with a ring cleavage reaction of the precursor, a potential intermediate of sorbicillinol biosynthesis. (c) 2007 Elsevier Ltd. All rights reserved.