A comparative study of CCM and hot-pressed MEAs for PEM fuel cells

A comparative study of CCM and hot-pressed MEAs for PEM fuel cells
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DOI:
10.1016/j.jpowsour.2007.03.062
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发表时间:
2007-06-30
影响因子:
9.2
通讯作者:
Pan, Mu
Pan, Mu
中科院分区:
工程技术2区
文献类型:
--
作者:
Tang, Haolin;Wang, Shenlong;Pan, Mu

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在相同的Pt电催化剂负载条件下,对由常规热压MEA和催化剂涂覆膜(CCM)制成的PEM燃料电池进行了比较研究。结果表明,与传统的热压膜电极制备的电池相比,CCM电池表现出显着更高的电化学性能和功率密度。循环伏安和交流阻抗研究表明,由CCM方法制备的膜电极具有更高的电化学表面积,低电池欧姆电阻和低电荷转移电阻相比,与热压膜电极和相同的Pt负载量。结果表明,CCM可以提高燃料电池的利用效率,改善催化剂层和膜界面。(C)2007 Elsevier B.V.保留所有权利。
A comparative investigation was performed on PEM fuel cells made with conventional hot-pressed MEAs and catalyst-coated membranes (CCM) under identical conditions of Pt electrolcatalyst loadings. The results showed that cells with a CCM exhibit significantly higher electrochemical performance and power density than those prepared with conventional hot-pressed MEAs. Cyclic voltammetric and impedance studies showed that the MEAs prepared by the CCM method have a higher electrochemical surface area, low cell ohmic resistance and low charge transfer resistance as compared to those prepared with hot-pressed MEAs and the same Pt loading. The results demonstrate that a CCM can enhance the utilization efficiency and improve the catalyst layer and membrane interface of PEM fuel cells. (C) 2007 Elsevier B.V. All rights reserved.