Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis
Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis
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DOI：
10.1039/c3cc42695e
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发表时间：
2013-01-01
影响因子：
4.9
通讯作者：
Akita, Munetaka
中科院分区：
文献类型：
--
作者：
Miyazawa, Kazuki;Yasu, Yusuke;Akita, Munetaka
已经开发出通过光氧化还原催化使用烷氧基甲基三氟硼酸盐对缺电子烯烃进行加氢烷氧基甲基化。通过可见光诱导的 SET 过程氧化烷氧基甲基三氟硼酸盐可以很容易地产生高反应性的烷氧基甲基自由基。
Hydroalkoxymethylation of electron-deficient alkenes using alkoxymethyltrifluoroborates by photoredox catalysis has been developed. Highly reactive alkoxymethyl radicals can be easily generated from oxidation of alkoxymethyltrifluoroborates via a visible-light-induced SET process.