Editorial on the special issue of JRS on Vibrational Spectroscopy of Water
Editorial on the special issue of JRS on Vibrational Spectroscopy of Water
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JRS 水振动光谱学特刊的社论
DOI：
10.1002/jrs.6451
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发表时间：
2022
期刊：
影响因子：
--
通讯作者：
and Hiro-o Hamaguchi
中科院分区：
文献类型：
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作者：
Shoichi Yamaguchi;Roumiana Tsenkova;and Hiro-o Hamaguchi
水是地球表面最丰富的化合物，也是所有生物体的主要组成部分，水的重要性怎么强调都不过分。水在科学和技术中发挥着广泛的核心作用。水的结构-性质关系与理解地球上的生命、深化地球科学、合成新材料、探索宇宙中的生命、发展化学工业等有关。关于水的结构-性质关系的许多已知信息来自振动光谱学。它允许在几乎任意的温度和压力下以最终的空间和时间分辨率研究任何相和形式的水。这是一个不可或缺的工具，以提高我们对水的认识。这期特刊的JRS展示了最近的进展，振动光谱的水从实验和理论的观点。值得注意的是，本期的论文采用了各种工具，如拉曼，IR，NIR，SFG（和频产生）和理论光谱，以研究水的应用为导向，以及基本方面。它还指出，这个问题涉及水在不同的环境：例如，结晶相，无定形状态，固体表面，软界面，离子液体，水化壳，散装常温和过冷液体，高压相，等液态水的微观结构仍然是一个问题的热议持续超过100年。在这期特刊中，Hamaguchi使用由最先进的多元曲线分辨率（MCR）分析提供动力的拉曼光谱解决了这个长期存在的问题。[1]Korepanov及其同事将超拉曼光谱应用于液态水，以获得对其氢键结构的新见解。[2]Ozaki和同事采用二维相关拉曼光谱来研究包括过冷水在内的液体结构的温度依赖性。[3]Inoue和Okuno使用超拉曼光谱研究了酸性溶液中水合质子的分子结构。[4]从新兴的水组学的角度来看，Shao等人进行了水和各种水体系的NIR和拉曼光谱，报告了氢键结构的新方面。[5]水溶液中的溶剂化结构也是许多化学分支学科中的重要问题。Hu等报道了水化结构的拉曼光谱研究
We cannot overstate the importance of water that is the most abundant compound on the surface of Earth and also the principal constituent of all living organisms. Water plays a central role in science and technology extensively. The structure-property relationship of water is pertinent to understanding life on Earth, deepening geoscience, synthesizing new materials, exploring the universe with quests for life, developing chemical industries, and so on. Much of what is known about its structure-property relationship comes from none other than vibrational spectroscopy. It allows for studying water in any phases and forms at almost arbitrary temperature and pressure with ultimate spatial and temporal resolution. It is an indispensable tool to advance our understanding of water.This special issue of JRS showcases recent advances in vibrational spectroscopy of water from experimental and theoretical viewpoints. One notes that the papers in this issue employ various tools such as Raman, IR, NIR, SFG (sum frequency generation), and theoretical spectroscopies to investigate water in application-oriented as well as fundamental aspects. It is also noted that this issue deals with water in diverse environments: eg, crystalline phases, amorphous states, solid surfaces, soft interfaces, ionic liquids, hydration shells, bulk ambienttemperature and supercooled liquids, high-pressure phases, etc. The microscopic structure of liquid water is still a matter of hot debate persisting for more than 100 years. In this special issue, Hamaguchi addressed this long-standing problem using Raman spectroscopy powered by state-of-the-art multivariate curve resolution (MCR) analysis.[1] Korepanov and coworkers applied hyper-Raman spectroscopy to liquid water for obtaining new insight into its hydrogen-bond structure.[2] Ozaki and coworkers employed two-dimensional correlation Raman spectroscopy to investigate the temperature dependence of the liquid structure including supercooled water.[3] Inoue and Okuno studied the molecular structure of hydrated protons in acidic solution using hyper-Raman spectroscopy.[4] From emerging aquaphotomics point of view, Shao et al. carried out NIR and Raman spectroscopy of water and various aqueous systems reporting new aspects of the hydrogen-bond structure.[5] The solvation structure in aqueous solution is also an important issue in most subdisciplines of chemistry. Hu and coworkers reported Raman spectroscopic study of the hydration structure