GLYCOSYLATION OF ACIDS UNDER PHASE-TRANSFER CONDITIONS - PARTIAL SYNTHESIS OF SAPONINS
GLYCOSYLATION OF ACIDS UNDER PHASE-TRANSFER CONDITIONS - PARTIAL SYNTHESIS OF SAPONINS
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DOI：
10.1016/0040-4039(94)88088-3
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发表时间：
1994-08-15
影响因子：
1.8
通讯作者：
NAZABADIOKO, S
中科院分区：
文献类型：
--
作者：
BLIARD, C;MASSIOT, G;NAZABADIOKO, S
以各种羧酸和乙酰溴糖为原料，高收率地制备了- d -糖基酯。该反应在相转移条件下使用碳酸钾。去乙酰化产生- d -糖基羧酸酯。
beta-D-glycosyl esters are prepared in high yields by reaction of various carboxylic acids and acetobromosugars. The reaction uses potassium carbonate under phase transfer conditions. Deacetylation affords the beta-D-glycosyl carboxylates.