novel homogeneous Fenton-like system with Fe ( III ) – phosphotungstate for xidation of organic compounds at neutral pH values

novel homogeneous Fenton-like system with Fe ( III ) – phosphotungstate for xidation of organic compounds at neutral pH values
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发表时间：
2009
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通讯作者：
hangha Lee;D. Sedlak
hangha Lee;D. Sedlak
中科院分区：
其他
文献类型：
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作者：
hangha Lee;D. Sedlak

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铁离子(Fe[III])通过铁对(Fe[II]/Fe[III])的氧化还原循环，催化过氧化氢(H_2O_2)分解成羟基自由基(·OH)和铁离子(Fe[IV])等强氧化剂。由于Fe(III)的低溶解度和在中性pH 3−下氧化剂的生成效率低，这些反应用于有机化合物的催化氧化通常限于酸性pH区
Ferric ion (Fe[III]) catalyzes the decomposition of hydrogen peroxide (H2O2) into strong oxidants such as hydroxyl radical (•OH) and ferryl ion (Fe[IV]) through the redox cycling of the iron couple (Fe[II]/Fe[III]). The use of these reactions for the catalytic oxidation of organic compounds is usually limited to the acidic pH region due to the low solubility of Fe(III) and the low efficiency of oxidant production at neutral pH 3−